Summary: Spherical colloids with isotropic properties have been used as building blocks to assemble a variety of 2D and 3D structures in past, such as FCC, HCP, and BCT crystals. Anisotropic particles are, however, more faithful mimics of molecules and atoms because of the anisotropic interactions. Current synthetic methods are versatile and accurate enough to create and tune the anisotropic properties in geometry, chemical composition, surface functionality, and physical properties. In the...